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Problem 1.16

12 November, 2015 - 15:03
Two atoms will interact via electrical forces between their protons and electrons. To put them at a distance r from one another (measured from nucleus to nucleus), a certain amount of energy E is required, and the minimum energy occurs when the atoms are in equilibrium, forming a molecule. Often a fairly good approximation to the energy is the Lennard-Jones expression
E(r)=k\left [ \left ( \frac{a}{r} \right )^{12}-2\left ( \frac{a}{r} \right )^6 \right ]
where k and a are constants. Note that, as proved in To infinity — and beyond!, the rule that the derivative of t^k is kt^{k-1} also works for k<0. Show that there is an equilibrium at r=a. Verify (either by graphing or by testing the second derivative) that this is a minimum, not a maximum or a point of inflection.

Solutions for chapter 1